| 1 |  André Greipel (GER) | Team HTC - Columbia | 4:13:17 |
| 2 |  Koldo Fernandez De Larrea (ESP) | Euskaltel - Euskadi | mt |
| 3 |  Manuel Antonio Cardoso Leal (POR) | Footon - Servetto | mt |
| 4 | José Joaquin Rojas Gil (ESP) | Caisse d'Epargne | mt |
| 5 |  Jens Keukeleire (BEL) | Cofidis, le Crédit en Ligne | mt |
| 6 | Fabian Wegmann (GER) | Team Milram | mt |
| 7 |  Jonas Aaen Jørgensen (DEN) | Saxo Bank | mt |
| 8 | Andreas Schillinger (GER) | Team Netapp | mt |
| 9 | Ruben Perez Moreno (ESP) | Euskaltel - Euskadi | mt |
| 10 |  Eduard Vorganov (RUS) | Team Katusha | mt |
| 11 | Christian Knees (GER) | Team Milram | mt |
| 12 | Jens Voigt (GER) | Saxo Bank | mt |
| 13 |  Bram Tankink (NED) | Rabobank | mt |
| 14 |  Jérôme Pineau (FRA) | Quick Step | mt |
| 15 | Vicente Reynès Mimo (ESP) | Team HTC - Columbia | 0:00:06 |
| 16 |  Laurent Didier (LUX) | Saxo Bank | 0:00:07 |
| 17 | Johannes Fröhlinger (GER) | Team Milram | mt |
| 18 | Iván Melero Coco (ESP) | Burgos 2016 - Castilla y Leon | mt |
| 19 | Paul Voss (GER) | Team Milram | mt |
| 20 | Romain Zingle (BEL) | Cofidis, le Crédit en Ligne | mt |
| 21 | Antonio Piedra Perez (ESP) | Andalucía - Cajasur | 0:00:10 |
| 22 | Iban Velasco Murillo (ESP) | Euskaltel - Euskadi | mt |
| 23 | Francis De Greef (BEL) | Omega Pharma - Lotto | mt |
| 24 |  Luke Roberts (AUS) | Team Milram | mt |
| 25 | Nico Sijmens (BEL) | Cofidis, le Crédit en Ligne | mt |
| 26 | David Deroo (FRA) | Skil - Shimano | mt |
| 27 | Daniel Moreno Fernández (ESP) | Omega Pharma - Lotto | mt |
| 28 | Ángel Vicioso Arcos (ESP) | Andalucía - Cajasur | mt |
| 29 |  David Vitoria (SUI) | Footon - Servetto | mt |
| 30 | Joan Sebastian Horrach Rippoll (ESP) | Team Katusha | mt |
| 31 | Alexandre Botcharov (RUS) | Team Katusha | mt |
| 32 | Luis León Sánchez Gil (ESP) | Caisse d'Epargne | 0:00:13 |
| 33 | Luis Pasamontes Rodriguez (ESP) | Caisse d'Epargne | mt |
| 34 | Jurgen Van Den Broeck (BEL) | Omega Pharma - Lotto | mt |
| 35 | Jan Bakelants (BEL) | Omega Pharma - Lotto | mt |
| 36 | Jean-Christophe Péraud (FRA) | Omega Pharma - Lotto | mt |
| 37 | Fränk Schleck (LUX) | Saxo Bank | mt |
| 38 | André Steensen (DEN) | Saxo Bank | mt |
| 39 | Raul Santamarta Valvuena (ESP) | Burgos 2016 - Castilla y Leon | mt |
| 40 |  Francesco Reda (ITA) | Quick Step | mt |
| 41 | Antonio Tauler Llull (ESP) | Equipo Nacional de España | 0:00:17 |
| 42 | Mikel Landa Meana (ESP) | Orbea | mt |
| 43 | Lars Boom (NED) | Rabobank | mt |
| 44 | Ion Izagirre Insausti (ESP) | Orbea | mt |
| 45 | Nick Nuyens (BEL) | Rabobank | mt |
| 46 |  Vasil Kiryienka (BLR) | Caisse d'Epargne | mt |
| 47 | Jelle Vanendert (BEL) | Omega Pharma - Lotto | mt |
| 48 |  Frederik Wilmann (NOR) | Skil - Shimano | mt |
| 49 | Alexandr Kolobnev (RUS) | Team Katusha | mt |
| 50 | Egor Silin (RUS) | Team Katusha | mt |
| 51 | Laurens Ten Dam (NED) | Rabobank | 0:00:20 |
| 52 | Maxime Monfort (BEL) | Team HTC - Columbia | mt |
| 53 | Chris Anker Sørensen (DEN) | Saxo Bank | mt |
| 54 |  Peter Velits (SVK) | Team HTC - Columbia | mt |
| 55 | Rodrigo García Rena (ESP) | Xacobeo - Galicia | mt |
| 56 | Kasper Klostergård Larsen (DEN) | Saxo Bank | mt |
| 57 |  Andrey Amador Bikkazakova (CRC) | Caisse d'Epargne | mt |
| 58 | Beñat Intxausti Elorriaga (ESP) | Euskaltel - Euskadi | 0:00:31 |
| 59 | Vladimir Karpets (RUS) | Team Katusha | 0:00:32 |
| 60 | Alberto Losada Alguacil (ESP) | Caisse d'Epargne | mt |
| 61 |  Markus Eibegger (AUT) | Footon - Servetto | mt |
| 62 | Rafael Valls Ferri (ESP) | Footon - Servetto | mt |
| 63 | Kim Kirchen (LUX) | Team Katusha | mt |
| 64 |  Tejay Van Garderen (USA) | Team HTC - Columbia | 0:00:41 |
| 65 | Maarten Tjallingii (NED) | Rabobank | 0:00:45 |
| 66 | Craig Lewis (USA) | Team HTC - Columbia | 0:01:08 |
| 67 | Jesus Rosendo Prado (ESP) | Andalucía - Cajasur | 0:01:53 |
| 68 | Oscar Grau Jorda (ESP) | Burgos 2016 - Castilla y Leon | 0:01:54 |
| 69 | Christophe Moreau (FRA) | Caisse d'Epargne | 0:04:24 |
| 70 | Pablo Lastras Garcia (ESP) | Caisse d'Epargne | mt |
| 71 | Rasmus Poulsen Guldhammer (DEN) | Team HTC - Columbia | mt |
| 72 | Thomas Berkhout (NED) | Van Vliet - Ebh - Elshof | mt |
| 73 |  Frantisek Rabon (CZE) | Team HTC - Columbia | mt |
| 74 | Rui Alberto Faria da Costa (POR) | Caisse d'Epargne | mt |
| 75 | Bert Grabsch (GER) | Team HTC - Columbia | mt |
| 76 | Maxime Vantomme (BEL) | Team Katusha | mt |
| 77 | Inaki Isasi Flores (ESP) | Euskaltel - Euskadi | mt |
| 90 | Bas Stamsnijder (NED) | Van Vliet - Ebh - Elshof | 0:09:07 |
| 91 | Tom Leezer (NED) | Rabobank | mt |
| 92 | Matthias Brändle (AUT) | Footon - Servetto | mt |
| 93 | Gregory Brenes Obando (CRC) | Burgos 2016 - Castilla y Leon | mt |
| 94 | Robbie McEwen (AUS) | Team Katusha | 0:09:14 |
| 95 | Joaquim Rodríguez Oliver (ESP) | Team Katusha | mt |
| 96 | Jakob Diemer Fuglsang (DEN) | Saxo Bank | 0:09:19 |
| 97 | Francisco Jose Pacheco Torres (ESP) | Xacobeo - Galicia | 0:12:15 |
